Luigi Vergori
Università di Perugia
Mechanics of nematic shells
Nematic liquid crystals are aggregates of rodlike molecules that
tend to align parallel to each other along a given direction.
Due to their easy response to externally applied electric,
magnetic, optical and surface fields, liquid crystals are of
greatest potential for scientific and technological
applications. In the last few decades, there has been an
increasing interest in soft matter physics on small spherical
colloidal particles or droplets coated with a thin layer of
nematic liquid crystal. The hope is to build mesoatoms with
controllable valence. These coating layers are referred to as
nematic shells. When nematic liquid crystals are constrained to
a curved surface, the geometry induces a distortion in the
molecular orientation. The possibility to have an in-plane order
rather than a spatial distribution of the molecules depends on
the shell thickness. In ultra-thin shells, the interaction with
the colloid surface enforces a sort of degenerate anchoring,
i.e., the tendency of the molecules to align parallel to the
surface. Thus, unavoidable defects arise when nematic order is
established on a surface with the same topology as that of the
sphere. Most theoretical studies on nematic liquid crystals are
framed within the classical director theory. In this setting,
the local properties of the nematic liquid crystals are
described through a unit vector, the director, parallel to the
local average molecular direction. However, the director
description of a nematic configuration misses a relevant
information at the mesoscopic level: the dispersion of the
molecules around the average molecular orientation. The
order-tensor theory, developed by the Nobel laureate
Pierre-Gilles de Gennes, overcomes this gap by introducing a
richer kinematic description. Within the framework of both the
order-vector and order-tensor theories, these lectures aim to
derive models for the free energy density of nematic shells from
well-established three-dimensional theories for liquid crystals,
to introduce suitable dissipation potentials and to develop a
rigorous variational approach for studying the statics and
dynamics of nematic shells.